Compressive impacts on the newly formed carbon serve in turn to increase the thermal conductivity of the carbon. [68]:16. / The process is illustrated by FIG. The biofuels are subject to a selective distillation process 540 that selects components whose final boiling points are between previously selected lower and upper limits. [21] Other military fuels are highly specialized products and are developed for very specific applications. Lignin-based chemicals and biomaterials will be feasible alternatives to their fossil-fuel-based counterparts once their breakdown into constituents is economically viable. The fuel compositions of the examples provide improved fuel economy benefits, good cleaniness and reduced friction by both hydrodynamic and boundary lubrication effects. Our goal in this project was to find a way to overcome the microbial inhibition and characterize . General health hazards associated with exposure to jet fuel vary according to its components, exposure duration (acute vs. long-term), route of administration (dermal vs. respiratory vs. oral), and exposure phase (vapor vs. aerosol vs. raw fuel). [50], The U.S. Air Force's C-17 Globemaster III, F-16 and F-15 are certified for use of hydrotreated renewable jet fuels. In one embodiment of the present invention, p is 1. No. [43][44][45][46][47][48], On February 8, 2021, the world's first scheduled passenger flight flew with some synthetic kerosene from a non-fossil fuel source. Jet fuel or aviation turbine fuel (ATF, also abbreviated avtur) is a type of aviation fuel designed for use in aircraft powered by gas-turbine engines. Conveniently, the gasoline may contain at least 0.5, 1.0 or 2.0 percent by volume oxygenated hydrocarbons. [49], On August 8, 2007, Air Force Secretary Michael Wynne certified the B-52H as fully approved to use the FT blend, marking the formal conclusion of the test program. 6a-6c show gas chromatograms (GC) of biofuel prior to distillation with no dehydration step (6a), a biofuel fraction collected in the temperature range 73C105C during the biofuel distillation between 0C and 188C, with dehydration step (6b), and biofuel component containing all combined collected fractions, with dehydration step (6c). In a preferred embodiment, said antioxidants are present in an amount in the range of from 0.1 to 5.0 percent by weight, more preferably in an amount in the range of from 0.3 to 3.0 percent by weight, and most preferably in an amount of in the range of from 0.5 to 1.5 percent by weight, based on the total weight of the lubricating oil composition. Full Record; Other Related Research Said boron-containing anti-wear additives may be conveniently added to the lubricating oil in an amount in the range of from 0.1 to 3.0 percent by weight, based on the total weight of lubricating oil composition. Process for preparing a liquid fuel composition. Privacy Policy and ester derivatives with polyols (glycerol, etc.) [7], The primary difference is the lower freezing point of A-1:[5]. Physical properties of liquid fuels vary by temperature, though not as greatly as for gaseous fuels. Fuel for piston-engine powered aircraft (usually a high-octane gasoline known as avgas) has a high volatility to improve its carburetion characteristics and high autoignition temperature to prevent preignition in high compression aircraft engines. The cars were run on additised fuel containing detergent package, friction modifier and viscosity control additive. The total content of the additives in the diesel fuel composition may be suitably between 0 and 10000 ppmw and preferably below 5000 ppmw. Because the exact composition of jet fuel varies widely based on petroleum source, it is impossible to define jet fuel as a ratio of specific hydrocarbons. It may also be co-blended with methanol, ethanol, propanol, butanol, butanediol, isobutanol, and vegetable oil. Also suitable for use herein are gasoline blending components which can be derived from a biological source. The lubricating oil composition may further comprise additives such as anti-oxidants, anti-wear additives, detergents, dispersants, friction modifiers, viscosity index improvers, pour point depressants, corrosion inhibitors, defoaming agents and seal fix or seal compatibility agents. 3,996,059, U.S. Pat. Temperature of ignition (K) 6. The first axial compressor jet engine in widespread production and combat service, the Junkers Jumo 004 used on the Messerschmitt Me 262A fighter and the Arado Ar 234B jet recon-bomber, burned either a special synthetic "J2" fuel or diesel fuel. However, it may also be used as a fuel, most often in combination with gasoline. [4] Other fuels used were kerosene or kerosene and gasoline mixtures. Further suitable carrier oil systems are described, for example, in DE-A-38 26 608, DE-A-41 42 241, DE-A-43 09 074, EP-A-0 452 328 and EP-A-0 548 617, which are incorporated herein by way of reference. The present invention therefore provides a method of improving the fuel economy performance of a liquid base fuel suitable for use in an internal combustion engine, comprising admixing at least one fuel additive having a kinematic viscosity at 100 C. of 27 cSt or less and a NOACK volatility at 250 C. of 100% wt, preferably 20 wt % or less, and at least one friction modifier with a major portion of a liquid base fuel suitable for use in an internal combustion engine. Ground particle size may range from 0.001 inch to 1 inch in diameter, limited by processing equipment size and thermal transfer rates. The liquid fuel composition contains a base fuel suitable for use in an internal combustion engine, a first fuel additive selected from viscosity control agents having certain physical properties and a second fuel additive which is a friction modifier. or improve a property of a fuel to prevent further engine wear. In one embodiment of the present invention the terminal amine group is NH2. Those skilled in the art will appreciate that functional groups such as hydroxy, halo, alkoxy, nitro and cyano in a substituted hydrocarbyl group Y will displace one of the hydrogen atoms of the hydrocarbyl, whilst functional groups such as carbonyl, carboxyl, tertiary amino (N), oxy, sulphonyl and sulphoxyl in a substituted hydrocarbyl group will displace a CH or CH2 moiety of the hydrocarbyl. The dehazer should be used in an amount sufficient to inhibit the hazing that might otherwise occur when the gasoline without the dehazer contacts water, and this amount will be referred to herein as a haze-inhibiting amount. Generally, this amount is from about 0.1 to about 20 ppmw (e.g. Conveniently, the gasoline may comprise a mixture of saturated hydrocarbons, olefinic hydrocarbons, aromatic hydrocarbons, and, optionally, oxygenated hydrocarbons. The additive blends from Table 1 are each blended into an EN228 gasoline fuel in an amount of 10 to 6000 ppmw, based on the total gasoline fuel composition. Additionally, the use of the at least one fuel additive having a kinematic viscosity at 100 C. of 27 cSt or less and a NOACK volatility at 250 C. of 100% wt, preferably 20 wt % or less, and at least one friction modifier in liquid fuel compositions can also provide benefits in terms of improving the fuel economy performance of a lubricant of an internal combustion engine being fuelled by the liquid fuel composition of the present invention. In each case the base fuel was pre-treated with the same commercial detergent additive package, and each fuel additionally contained a test additive at a concentration detailed in Table 4. A typical commercial mixture may also contain ethane and ethylene, as well as a volatile . For example, the oxygen content of the gasoline may be up to 25 percent by weight, preferably up to 10 percent by weight. There are no particular limitations regarding the lubricating oil used in the lubricating oil composition, and various conventional known mineral oils and synthetic oils may be conveniently used. the paper by Danping Wei and H. A. Spikes, The Lubricity of Diesel Fuels, Wear, III (1986) 217-235; WO-A-95/33805cold flow improvers to enhance lubricity of low sulphur fuels; U.S. Pat. Materials and Methods. an alkoxide, phenoxide or enolate anion), nitrogen based anions such as nitrate and nitrite, phosphorus based anions such as phosphates and phosphonates, or mixtures thereof. 90% recovery is achieved by a temperature of 480F. More preferably, the poly(hydroxycarboxylic acid) amide salt derivatives each have a TBN value of less than 5 mg.KOH/g, most preferably 2 mg.KOH/g or less, as measured by ASTM D 4739. When the pre-distillation material is subjected to dehydration with 3A zeolite, Fig. The lubricating oil compositions may additionally contain an ash-free dispersant which is preferably admixed in an amount in the range of from 5 to 15 percent by weight, based on the total weight of the lubricating oil composition. However, there is no tax regulation in the Chicago Convention to refuel the aircraft before departure. The color of the electronic cigarette is generally golden yellow or colorless liquid. at the refinery, it will contain minor amounts of one or more additives selected for example from anti-static agents, pipeline drag reducers, flow improvers (e.g. Some are almost identical to their civilian counterparts and differ only by the amounts of a few additives; Jet A-1 is similar to JP-8, Jet B is similar to JP-4. 6 exclusive of volatile solvents/diluent materials. The optionally substituted hydrocarbyl group Y in formula (I) herein is preferably aryl, alkyl or alkenyl containing up to 50 carbon atoms, more preferably in the range of from 7 to 25 carbon atoms. Most liquid fuels used currently are produced from petroleum. Various concept hydrogen vehicles have been lower volumetric energy, the hydrogen volumes needed for combustion are large. The poly(hydroxycarboxylic acid) derivatives having a terminal amine group that are preferred in the present invention are those which each have a TBN (total base number) value of at least 100 mg.KOH/g, more preferably at least 150 mg.KOH/g, even more preferably at least 175 mg.KOH/g and most preferably at least 200 mg.KOH/g, as measured by ASTM D 4739. Certain of these components are used in Examples 2 to 5. The TAN may be at least 0 mg.KOH/g. Government regulations and market demands continue to emphasize conservation of fossil fuels in the transportation industry. These substances are called exhaust. Conveniently, the fuel additives can be blended with one or more solvents to form an additive concentrate, the additive concentrate can then be admixed with the base gasoline or the gasoline composition of the present invention. In the following example, three commercially available friction modifiers (FM) were used: FM10this is a reaction product of oleic acid and aminoethylethanolamine having a 3:1 molar ratio as per Example 4 of WO2009/50287. Suitable types of hyperdispersants for use herein include those disclosed in WO2010/012756, WO2010/012763, PCT application number PCT/EP2010/070723 and PCT/EP2010/070762. In addition, small quantities of nitrogen may be present. 500 ppmw or less) sulphur content. A liquid fuel composition containing a biofuel component, produced from a fraction of one or more cracking products produced by catalytic cracking of a biomass source. In the compounds of formulae (I) and (II), the optional substituents in the group A are preferably selected from hydroxy, halo or alkoxy groups, more preferably C1-4 alkoxy groups. = Examples of detergents suitable for use in diesel fuel additives for the present purpose include polyolefin substituted succinimides or succinamides of polyamines, for instance polyisobutylene succinimides or polyisobutylene amine succinamides, aliphatic amines, Mannich bases or amines and polyolefin (e.g. More preferably, A is an arylene, alkylene or alkenylene group, in particular an arylene, alkylene or alkenylene group containing in the range of from 4 to 25 carbon atoms, more preferably in the range of from 6 to 25 carbon atoms, more preferably in the range of from 8 to 24 carbon atoms, more preferably in the range of from 10 to 22 carbon atoms, and most preferably in the range of from 12 to 20 carbon atoms. The hydrocarbyl group Y in formula (I) is more preferably unsubstituted or substituted by a group selected from hydroxy, halo or alkoxy group, even more preferably C1-4 alkoxy. [3] For reasons of inter-operational ability, British and United States military standards are harmonized to a degree. Most liquid fuels in widespread use are derived from fossil fuels; however, there are several types, such as hydrogen fuel (for automotive uses), ethanol, and biodiesel, which are also categorized as a liquid fuel. Crude oil is usually black or dark brown but can also be yellowish reddish tan or even greenish.Variations in color indicate the distinct chemical compositions of different supplies of crude oil. In Chapter 18, the advantages and disadvantages of liquid metal fuels were discussed in a general way. Paraffinic lubricating oils have higher VI (generally >95) and a high pour point. Both these gases at room temperature are colourless and odourless. Suitable alkyl-substituted naphthalenes include alpha-methylnaphthalene, dimethylnaphthalene and ethylnaphthalene. In some cases, the gasoline composition contains a first fuel component, comprising one or more C4+ compounds derived from biomass conversion using ramps of temperature under pressure, wherein the fuel component has a component initial boiling point of in the range of 0C and 70C and a component final boiling point in the range of 85C and 225C, a component density at 20C in the range of 600 to 990 kg/m3, a component sulfur content of at most 10 mg/kg, a component RON in the range of 80 to 120 and a component MON in the range of 75 to 110. Examples of suitable polyolefins are olefin polymers, in particular based on polybutene or polyisobutene (hydrogenated or nonhydrogenated). The fuel is a kind of kerosene, made from passing electricity through a mixture of carbon dioxide and water. One approach to this problem is to write the combustion equation for each of the combustible elements per 100 kg of fuel. Other lubricity enhancers are described in the patent literature, in particular in connection with their use in low sulphur content diesel fuels, for example in: It may also be preferred for the diesel fuel composition to contain an anti-foaming agent, more preferably in combination with an anti-rust agent and/or a corrosion inhibitor and/or a lubricity enhancing additive. Biomass 51 is pretreated in operation 410 prior to being subjected to the bio-fractioning process 420. Synthetic processes enable molecules to be built from simpler substances or to have their structures modified to give the precise properties required. When the acid is polycarboxylic, having for example from 2 to 4 carboxy groups, the hydrocarbyl group is preferably a substituted or unsubstituted polymethylene. a propane-1,2-diol semi-ester of tetrapropenyl succinic acid, or polyhydric alcohol esters of a succinic acid derivative, the succinic acid derivative having on at least one of its alpha-carbon atoms an unsubstituted or substituted aliphatic hydrocarbon group containing from 20 to 500 carbon atoms, e.g. Preferably, the amount of the first fuel additive having a viscosity of less than 27 cSt and a NOACK volatility of 100% wt or less, preferably 20% wt or less, present in the liquid fuel composition of the present invention is at least 5 ppmw (parts per million by weight), based on the overall weight of the liquid fuel composition. Remember, the oxidizer helps the fuel burn. CHAPTER 20 COMPOSITION AND PROPERTIES OF LIQUID-METAL FUELS 95 20-1. Examples of poly(hydroxycarboxylic acid) amide salt derivatives having a formula (III) that are available commercially include that available from Lubrizol under the trade designation SOLSPERSE 17000 (a reaction product of poly(12-hydroxystearic acid) with N,N-dimethyl-1,3-propanediamine and dimethyl sulphate) and those available under the trade designations CH-5 and CH-7 from Shanghai Sanzheng Polymer Company. g The distillation or boiling range of the fuel depends on the fuel chemical composition and, therefore, influences other properties such as viscosity, flash point, autoignition . Viscosity control additives such as polyalphaolefins and esters are known for use in liquid fuel compositions and have been disclosed in the following patent publications: EP-A-707058; EP-A-290088; EP-A-634472; WO98/11178 and WO98/11177. Regardless of the source and production process, kerosenes and jet fuels primarily consist of C9 to C16 hydrocarbons that boil in the range of 145-300C (API 2010a). Such esters may, for example, be obtained by saponification and esterification of natural fats and oils of plant or animal origin or by their transesterification with lower aliphatic alcohols. for buses in Belgium during WWII). The latter two processes produce C2-C6 oxygenates and sugar alcohols, which are typically subjected to Pt/Ru catalysts in order to form gasoline precursors. p is selected from 2 to 10, from 2 to 8, or from 2 to 6). Such lubricating oils are produced from feedstocks rich in naphthenes and low in wax content and are used mainly for lubricants in which colour and colour stability are important, and VI and oxidation stability are of secondary importance. Likewise, where this document refers to technologies that would be apparent or known to one of ordinary skill in the art, such technologies encompass those apparent or known to the skilled artisan now or at any time in the future. A short time after peak pressure is applied, the anvil is pushed back by the pressure of extracted volatile compounds. The cost of butanol is about $1.25$1.32 per kilogram ($0.57-$0.58 per pound or $4 approx. 4 is a distillation curve showing the % recovered biofuel material as a function of distillation vapor temperature. Preferred friction modifiers for use herein are hyperdispersants selected from poly(hydroxycarboxylic) acid amide salt derivatives, poly(hydroxycarboxylic acid) derivatives having a terminal acid group, poly(hydroxycarboxylic acid) derivatives, and polyetheramines; nitrogen derivatives of alkoxyamines, alkoxylated amides or esters; and alkoxylated amines. Where the hydroxyl group in the hydroxycarboxylic acid is secondary or tertiary, the temperature employed should not be so high as to lead to dehydration of the acid molecule. for use as surfactant suitable for stabilising dispersions of solids in organic liquids and oil/water emulsions. 4,877,416. The amount of performance package(s) in the additive blend is preferably in the range of from 0.1 to 99.8 wt %, by weight of the additive blend. 3,454,555, U.S. Pat. In formula (VII), X is terminal amine group or a group carrying a terminal amine group, wherein the terminal amine group is selected from NR12, wherein R1 is selected from hydrogen and a C1-C6 hydrocarbyl group. The lubricating oil preferably has a sulphated ash content of not greater than 1.0 percent by weight, more preferably not greater than 0.75 percent by weight and most preferably not greater than 0.7 percent by weight, based on the total weight of the lubricating oil.
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